Anodes and Cathodes (GCSE Chemistry)

Anodes and Cathodes

The Anode and Cathode

  • There are two electrodes. One electrode is positive, whilst the other is negative. Both will direct current through an electrolyte, which the substance being split.
  • The anode is positive. The anode is the positive electrode and attracts negative ions. Here, the ions lose electrons, so are oxidised. Metals or hydrogen are usually formed at the anode.
  • The cathode is negative. The cathode is the negative electrode and attracts positive ions. Here, the ions gain electrons, so are reduced. Non metals are usually formed at the cathode.

Practice Question 1: Write out the half equations for Aluminium Oxide, stating which is reduced and which is oxidised.

2Al2O3 4Al + 3O2

GCSE Chemistry - Anodes and Cathodes
GCSE Chemistry – Anodes and Cathodes
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    Practice Question 2: Write out the half equations for Sodium Chloride, stating which is reduced and which is oxidised.

    2H+ + 2Cl H2 + Cl2

    GCSE Chemistry - Anodes and Cathodes
    GCSE Chemistry – Anodes and Cathodes

    When a halide isn’t present in the solution, we have a different half equation at the anode:

    4OH O2 + 2H2O + 4e

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