Equilibrium Constant for Homogeneous System - Changing Kp (A-Level Chemistry)

Changing Kp

How Temperature Affects the Value Kp

Changing the temperature of a reaction also changes the value of Kp because changing the temperature changes the amount of product formed.

This in turn changes the number of moles on each side of the equation, therefore the mole fractions and the partial pressure of each reactant is different.

This changes the value of Kp that is calculated.

 

Forward direction: exothermic reaction

  • Increase the temperature – Equilibrium shifts in the reverse direction, to favour the endothermic reaction, and so reduce the temperature.
    • The yield of products decreases.
    • The partial pressures of the products will decrease, therefore Kp will decrease.
  • Decrease the temperature – Equilibrium shifts in the forward direction, to favour the exothermic reaction, and increase the temperature.
    • More products are formed.
    • The partial pressure of the products will increase, therefore Kp will increase.

 

Forward direction: endothermic reaction

  • Increase the temperature – Equilibrium shifts in the forward direction, to favour the endothermic reaction and reduce the temperature.
    • More products are formed.
    • The partial pressure of the products will increase, therefore Kp will increase.
  • Decrease the temperature – Equilibrium shifts in the reverse direction, to favour the exothermic reaction and increase temperature.
    • The yield of products decreases.
    • The partial pressures of the products will decrease, therefore Kp will decrease.

 

Summary

Changing Kp
Changing Equilibrium Constant (Kp) in Homogeneous Systems

 

Effect of Pressure and Catalysts on Kp

Effect of adding a Catalyst

Similar to Kc, adding a catalyst does not affect the value of Kp.

A catalyst simply allows equilibrium to be reached sooner. A catalyst will affect the rate of reaction in both directions by the same amount.

 

Effect of changing the Pressure

Pressure does not affect the value of Kp, just as concentration does not affect the value of Kc.

An increase in pressure causes equilibrium to shift in favor of the direction with the fewer moles so that the pressure decreases.

The partial pressure ratio of reactant to products stays the same so Kp does not change.

 

 

FAQs

→What is equilibrium constant (Kp) in homogeneous system?

In a homogeneous system, the equilibrium constant is a quantitative measure of the extent to which a chemical reaction has reached equilibrium. It is denoted by the symbol K and is defined as the ratio of the product of the equilibrium concentrations of the products raised to their stoichiometric coefficients, divided by the product of the equilibrium concentrations of the reactants raised to their stoichiometric coefficients, with each concentration term raised to the power of its stoichiometric coefficient:

K = [C]^c[D]^d / [A]^a[B]^b

where [A], [B], [C], and [D] are the equilibrium concentrations of the reactants and products, and a, b, c, and d are the stoichiometric coefficients of the reactants and products, respectively.

The equilibrium constant is a characteristic property of a particular reaction at a specific temperature, and is independent of the initial concentrations of the reactants. It can be used to predict the direction in which a reaction will proceed under certain conditions, based on the value of K and the concentrations of the reactants and products.

If the value of K is greater than 1, then the equilibrium lies towards the products, meaning the reaction has a high tendency to proceed in the forward direction. Conversely, if the value of K is less than 1, then the equilibrium lies towards the reactants, meaning the reaction has a high tendency to proceed in the reverse direction. If the value of K is equal to 1, then the concentrations of the reactants and products are equal at equilibrium, and the reaction is said to be at equilibrium.

→How is the equilibrium constant (Kp) calculated?

The Kp can be calculated using the following formula: Kp = [C]^c * [D]^d / [A]^a * [B]^b, where [A], [B], [C], and [D] are the concentrations of reactants and products, and a, b, c, and d are the stoichiometric coefficients for each species.

→What happens when the Kp changes?

When the Kp changes, it affects the distribution of reactants and products in a reaction. If the Kp increases, the concentration of products will increase and the concentration of reactants will decrease. If the Kp decreases, the opposite will happen, with the concentration of reactants increasing and the concentration of products decreasing.

→How does a change in temperature affect the Kp?

A change in temperature can affect the Kp of a reaction. Generally, an increase in temperature will cause an increase in the Kp value, while a decrease in temperature will cause a decrease in the Kp value. This is because temperature affects the rate of reaction and the energy required for a reaction to occur.

→How does a change in pressure affect the Kp?

A change in pressure can also affect the Kp of a reaction. If a reaction involves a change in the number of moles of gas, a change in pressure will affect the Kp value. For example, if a reaction produces gas, an increase in pressure will increase the Kp value, while a decrease in pressure will decrease the Kp value.

→How can the Kp be used to predict the direction of a reaction?

The Kp can be used to predict the direction of a reaction by comparing the Kp value to the initial concentrations of reactants and products. If the Kp is greater than 1, the reaction will proceed to the right, favoring the formation of products. If the Kp is less than 1, the reaction will proceed to the left, favoring the formation of reactants. If the Kp is equal to 1, the reaction is at equilibrium and the concentration of reactants and products will not change.

→What are some real-world applications of the Kp?

The Kp can be used in various real-world applications, including the design of chemical reactors, the optimization of chemical processes, and the prediction of the behavior of chemical systems. It is also useful in understanding the behavior of equilibria in biological systems, such as in the regulation of blood pH. Understanding the Kp is essential for making informed decisions in a wide range of industries and applications.

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